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作者:

Wang, Feng (Wang, Feng.) | Sun, Jihong (Sun, Jihong.) (学者:孙继红) | Bai, Shiyang (Bai, Shiyang.) | Wu, Xia (Wu, Xia.) | Wang, Jinpeng (Wang, Jinpeng.)

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EI Scopus SCIE

摘要:

Hybrid bimodal mesoporous silica grafted 1,8-naphthalic anhydride (NA) as a luminescent tracer was modified by Eu3+ ions, whereas the influence of the interaction between europium salts with various anions (Cl-, NO3-, and CH3COO-) and NA molecules grafted onto the mesopores on their thermal decomposition behaviors and kinetic properties were studied in detail in accordance with the thermogravimetric analyzer (TGA) profiles obtained at different heating rates under flowing N-2 atmosphere. Meanwhile, Kissinger and Flynn-Wall-Ozawa algorithms were used to calculate the apparent activation energies of Eu3+-modified NA existing in the mesoporous channels and therefore the thermal decomposition mechanism was discussed on the basis of the Coats-Redfern method. Moreover, XRD, TEM, N-2 adsorption-desorption isotherms and FT-IR techniques were employed to analyze the structural characteristics and textural properties of the resultant samples. (C) 2014 Elsevier B.V. All rights reserved.

关键词:

1,8-Naphthalic anhydride Apparent activation energy Eu3+ ions Mesoporous silica Thermal decomposition behavior

作者机构:

  • [ 1 ] [Wang, Feng]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Sun, Jihong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Bai, Shiyang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Xia]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Jinpeng]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 孙继红

    [Sun, Jihong]Beijing Univ Technol, Coll Environm & Energy Engn, 100 PingLeYuan, Beijing 100124, Peoples R China

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来源 :

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS

ISSN: 0927-7757

年份: 2014

卷: 453

页码: 142-148

5 . 2 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:195

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 4

SCOPUS被引频次: 4

ESI高被引论文在榜: 0 展开所有

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