收录:
摘要:
Hybrid bimodal mesoporous silica grafted 1,8-naphthalic anhydride (NA) as a luminescent tracer was modified by Eu3+ ions, whereas the influence of the interaction between europium salts with various anions (Cl-, NO3-, and CH3COO-) and NA molecules grafted onto the mesopores on their thermal decomposition behaviors and kinetic properties were studied in detail in accordance with the thermogravimetric analyzer (TGA) profiles obtained at different heating rates under flowing N-2 atmosphere. Meanwhile, Kissinger and Flynn-Wall-Ozawa algorithms were used to calculate the apparent activation energies of Eu3+-modified NA existing in the mesoporous channels and therefore the thermal decomposition mechanism was discussed on the basis of the Coats-Redfern method. Moreover, XRD, TEM, N-2 adsorption-desorption isotherms and FT-IR techniques were employed to analyze the structural characteristics and textural properties of the resultant samples. (C) 2014 Elsevier B.V. All rights reserved.
关键词:
通讯作者信息:
电子邮件地址:
来源 :
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN: 0927-7757
年份: 2014
卷: 453
页码: 142-148
5 . 2 0 0
JCR@2022
ESI学科: CHEMISTRY;
ESI高被引阀值:258
JCR分区:2
中科院分区:3