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作者:

Liu, Shufeng (Liu, Shufeng.) | Zhang, Xin (Zhang, Xin.) | Yu, Yanmin (Yu, Yanmin.) | Zou, Guizheng (Zou, Guizheng.)

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摘要:

The development of electrochemiluminescence (ECL) emitters over a broad spectrum of wavelengths is anticipated for the multiplexed ECL sensing and diagnostic application. Herein, a facile dual-stabilizers-capped strategy was developed for synthesizing a series of water-soluble CdSe nanocrystals (NCs) with strong, bandgap engineered and monochromatic ECL emissions in greenish region. The linkage of surface cadmium atoms to the dual stabilizers, mercaptopropionic acid and sodium hexametaphosphate, not only can effectively remove the nonradiative surface state and deep surface trap of CdSe NCs for improved ECL efficiency and monochromaticity, but is also favorable for the electrochemical involved electron and hole injection processes for higher ECL intensity. ECL spectra of dual-stabilizers-capped CdSe NCs are narrow and much close to corresponding photoluminescence spectra, which indicates a series of bandgap engineered and monochromatic ECL emitters. The ECL signal of dual-stabilizers-capped CdSe NCs also shows acceptable accuracy and precision for the detection of dopamine concentration in the practical drug (dopamine hydrochloride injection). (C) 2013 Elsevier B.V. All rights reserved.

关键词:

Nanocrystals CdSe Monochromatic Bandgap engineered Electrochemiluminescence One-pot synthesis

作者机构:

  • [ 1 ] [Liu, Shufeng]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
  • [ 2 ] [Zhang, Xin]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
  • [ 3 ] [Zou, Guizheng]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
  • [ 4 ] [Yu, Yanmin]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zou, Guizheng]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

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来源 :

BIOSENSORS & BIOELECTRONICS

ISSN: 0956-5663

年份: 2014

卷: 55

页码: 203-208

1 2 . 6 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:258

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 47

SCOPUS被引频次: 48

ESI高被引论文在榜: 0 展开所有

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