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作者:

Sang, Lixia (Sang, Lixia.) (学者:桑丽霞) | Cai, Meng (Cai, Meng.) | Ren, Nan (Ren, Nan.) | Wu, Yuting (Wu, Yuting.) (学者:吴玉庭) | Burda, Clemens (Burda, Clemens.) | Ma, Chongfang (Ma, Chongfang.)

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EI Scopus SCIE

摘要:

In order to meet the requirements of high temperature solar thermal power generation better, the melting point of mixed carbonates should be further reduced. Starting with ternary carbonates, we modified their composition ratios and added NaNO3 or NaOH as additives. Their new melting points, initial crystallization points, decomposition temperatures, specific heats and thermal stabilities were analyzed. While the melting points of the mixed nitrate/carbonate salts were maintained at 394.7 degrees C, the melting points of the mixed hydroxide/carbonate salts were reduced to 323.2 degrees C. Also the initial crystallization temperature of the mixed hydroxide/carbonate salts was dependent on their composition. Among the hydroxide-mixed molten salts, there are six samples with lower initial crystallization temperature. The decomposition temperature of the selected six samples was nearly 800 degrees C. Their specific heats were fitted with the quadratic polynomial of the temperature and their thermal stability was shown by the excellent repeatability of five heating curves. Only the very first heating curves showed that the initial measured value of a melting point was higher than all the later values of the molten salts due to starting with the powder. Furthermore, possible issues that arise with the addition of NaOH are discussed. (c) 2014 Elsevier B.V. All rights reserved.

关键词:

Decomposition temperature Initial crystallization point Melting point Mixed molten salts Specific heat Thermal stability

作者机构:

  • [ 1 ] [Sang, Lixia]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 2 ] [Cai, Meng]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 3 ] [Ren, Nan]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Yuting]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 5 ] [Ma, Chongfang]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 6 ] [Sang, Lixia]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Cai, Meng]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Ren, Nan]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 9 ] [Wu, Yuting]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 10 ] [Ma, Chongfang]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 11 ] [Burda, Clemens]Case Western Reserve Univ, Dept Chem, Ctr Chem Dynam & Nanomat Res, Cleveland, OH 44106 USA

通讯作者信息:

  • 桑丽霞

    [Sang, Lixia]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China

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来源 :

SOLAR ENERGY MATERIALS AND SOLAR CELLS

ISSN: 0927-0248

年份: 2014

卷: 124

页码: 61-66

6 . 9 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:256

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 29

SCOPUS被引频次: 36

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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