收录:
摘要:
Structure, magnetic properties, and thermal stability of ternary Sm1-x Tm (x) Co-5 compounds were studied via X-ray diffraction (XRD), thermal magnetic analysis (TMA), and magnetic measurements. XRD results show that all the compounds have a main phase of hexagonal CaCu5-type crystal structure with small amount of impurity phases; increasing Tm content is associated with contraction of the hexagonal unit cell in the direction of the c axis and expansion of the a and b parameters. TMA results indicate that the Curie temperature (T (C)) of Sm1-x Tm (x) Co-5 compounds gets higher with the increase in Tm content. Magnetic measurements show that both the magnetic anisotropy field (H (A)) and the magnetization at an applied field of 7 T (M (7 T)) decrease with the increase of Tm content. However, the thermal stability of both the H (A) and M (7 T) of all the Tm doped compounds is remarkably improved compared with that of the pure SmCo5 compound, leading to the result that both the M (7 T) and H (A) of Sm0.8Tm0.2Co5.2 are higher than those of SmCo5 compound at 473 K, which indicates the good potential of Tm doped compound in the practical applications at elevated temperature.
关键词:
通讯作者信息:
电子邮件地址:
来源 :
RARE METALS
ISSN: 1001-0521
年份: 2014
期: 2
卷: 33
页码: 176-179
8 . 8 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:341
JCR分区:2
中科院分区:4