A　new　family　of　axially　unfixed　biaryl-based　water-compatible　bifuctional　organocatalysts　were　designed　and　synthesized　for　the　asymmetric　direct　Michael　reaction　of　cyclohexanone　with　various　nitroolefins　in　water.　One　of　the　organocatalysts　incorporates　pyrrolidine　and　arylsulfonamide　motifs　as　active　organocatalytic　sites,　and　axially　unfixed　biaryl　as　a　skeleton;　with　this　organocatalyst,　the　direct　Michael　reactions　proceeded　readily,　furnishing　the　desired　Michael　adducts　in　high　yields　(up　to　99%　yield)　with　high　levels　of　stereocontrol　(up　to　＞99:1　dr　and　94%　ee).