Inspired　by　the　complementary　roles　of　surface　energy　and　roughness　on　natural　nonwetting　surfaces,　a　superhydrophobic　surface　has　been　successfully　designed　and　prepared　by　self-assembled　monolayer　modification　on　a　hierarchical　ZIF-8/polymer　hybrid　membrane.　The　as-prepared　membrane　exhibited　the　best　overall　performance　for　n-butanol　pervaporation.