Ti/BMM　(bimodal　mesoporous　silica)　catalysts　have　been　prepared　via　a　self-assembly　route　combined　with　a　ship-in-a-bottle　technique.　Four　different　methods　were　carried　out　to　investigate　the　effects　of　adding　ionic　liquid　[spmim][Cl-]　(1-methyl-3-(3-trimethoxysilane)　propylimidazole　chloride)　and　triethanolamine　(TEAOH)　or　triethylamine　(TEA)　to　the　coordination　environment　of　the　titanium　species　in　the　mesopores.　The　structural　characteristics　and　textural　properties　of　resultant　samples　were　characterized　by　XRD,　FT-IR　spectroscopy,　N-2　adsorption-desorption　isotherms,　TGA,　and　UV-Vis　spectroscopy.　The　results　showed　that　the　bimodal　mesoporous　structure　of　Ti/BMMs　could　be　preserved　after　grafting　Ti　species　via　four　preparation　methods.　On　the　other　hand,　the　presence　of　[spmim][Cl-]　and　TEAOH　or　TEA　could　not　only　prevent　titanium　species　existing　on　the　mesoporous　surface　from　aggregating,　but　also　promote　loading　of　tetrahedrally-coordinated　titanium　species　with　a　high　dispersion.　Finally,　their　catalytic　activities　in　the　epoxidation　of　cyclohexene　preliminarily　indicated　that　the　influence　of　Ti　loading　methods　on　the　conversion　of　cyclohexene　was　remarkable.