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作者:

Zhang, Ziying (Zhang, Ziying.) | Xu, Pingping (Xu, Pingping.) | Weng, Ying (Weng, Ying.) | Zhou, Yangyang (Zhou, Yangyang.) | Sun, Zaicheng (Sun, Zaicheng.) (学者:孙再成) | Xiong, Shisheng (Xiong, Shisheng.)

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EI SCIE

摘要:

NiO-based flexible anodes have provoked great interest due to their high theoretical capacity, benign redox reactivity, and chemical and thermal stability. However, the issues of their poor cyclability, low rate capability, and mechanical instability limit their practical applications. To approach the high-performance flexible devices, 3D NiO/TiO2 nanotube network arrays on flexible carbon cloth substrates are fabricated through a simple two-step, seed-free solvothermal method. The ultrathin NiO nanosheets provide remarkable charge-discharge cycle performance due to their slight volume expansion during the charge-discharge process. The flexible carbon cloth provides a conductive and bendable matrix. TiO2 nanotube arrays not only deliver a fast electron transfer path, but also excellent mechanical stability during bending. The porous network architecture results in a remarkable reduction in the irreversible capacity loss without sacrificing specific surface area. This unique structure creates a reversible capacity of 592.2 mAh g(-1) after 1000 cycles at a current density of 200 mA g(-1), and has a rate capacity of 439 mAh g(-1) even at high current densities of 2000 mA g(-1). Their full cells maintain excellent electrochemical performance and mechanical stability after multiple folds. The convenient synthetic process creates a window of opportunity for bringing flexible, high-performance energy storage devices to markets. (C) 2020 Elsevier B.V. All rights reserved.

关键词:

Carbon cloth Lithium-ion battery anodes Nanotube arrays Nickel oxide Titanium dioxide

作者机构:

  • [ 1 ] [Zhang, Ziying]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 2 ] [Xu, Pingping]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 3 ] [Weng, Ying]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 4 ] [Zhou, Yangyang]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 5 ] [Sun, Zaicheng]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Ctr Excellence Environm Safety & Biol Effects, Beijing 100124, Peoples R China
  • [ 6 ] [Xiong, Shisheng]Fudan Univ, Sch Informat Sci & Engn, Shanghai 200433, Peoples R China

通讯作者信息:

  • 孙再成

    [Zhang, Ziying]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China;;[Sun, Zaicheng]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Ctr Excellence Environm Safety & Biol Effects, Beijing 100124, Peoples R China;;[Xiong, Shisheng]Fudan Univ, Sch Informat Sci & Engn, Shanghai 200433, Peoples R China

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来源 :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

年份: 2020

卷: 847

6 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:37

JCR分区:1

被引次数:

WoS核心集被引频次: 4

SCOPUS被引频次: 5

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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