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Author:

Zhang, Ziying (Zhang, Ziying.) | Xu, Pingping (Xu, Pingping.) | Weng, Ying (Weng, Ying.) | Zhou, Yangyang (Zhou, Yangyang.) | Sun, Zaicheng (Sun, Zaicheng.) (Scholars:孙再成) | Xiong, Shisheng (Xiong, Shisheng.)

Indexed by:

EI Scopus SCIE

Abstract:

NiO-based flexible anodes have provoked great interest due to their high theoretical capacity, benign redox reactivity, and chemical and thermal stability. However, the issues of their poor cyclability, low rate capability, and mechanical instability limit their practical applications. To approach the high-performance flexible devices, 3D NiO/TiO2 nanotube network arrays on flexible carbon cloth substrates are fabricated through a simple two-step, seed-free solvothermal method. The ultrathin NiO nanosheets provide remarkable charge-discharge cycle performance due to their slight volume expansion during the charge-discharge process. The flexible carbon cloth provides a conductive and bendable matrix. TiO2 nanotube arrays not only deliver a fast electron transfer path, but also excellent mechanical stability during bending. The porous network architecture results in a remarkable reduction in the irreversible capacity loss without sacrificing specific surface area. This unique structure creates a reversible capacity of 592.2 mAh g(-1) after 1000 cycles at a current density of 200 mA g(-1), and has a rate capacity of 439 mAh g(-1) even at high current densities of 2000 mA g(-1). Their full cells maintain excellent electrochemical performance and mechanical stability after multiple folds. The convenient synthetic process creates a window of opportunity for bringing flexible, high-performance energy storage devices to markets. (C) 2020 Elsevier B.V. All rights reserved.

Keyword:

Nanotube arrays Nickel oxide Carbon cloth Titanium dioxide Lithium-ion battery anodes

Author Community:

  • [ 1 ] [Zhang, Ziying]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 2 ] [Xu, Pingping]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 3 ] [Weng, Ying]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 4 ] [Zhou, Yangyang]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
  • [ 5 ] [Sun, Zaicheng]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Ctr Excellence Environm Safety & Biol Effects, Beijing 100124, Peoples R China
  • [ 6 ] [Xiong, Shisheng]Fudan Univ, Sch Informat Sci & Engn, Shanghai 200433, Peoples R China

Reprint Author's Address:

  • 孙再成

    [Zhang, Ziying]Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China;;[Sun, Zaicheng]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Ctr Excellence Environm Safety & Biol Effects, Beijing 100124, Peoples R China;;[Xiong, Shisheng]Fudan Univ, Sch Informat Sci & Engn, Shanghai 200433, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2020

Volume: 847

6 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:169

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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