Two　nucleobase-incorporated　metal-organic　materials　were　designed,　synthesized　and　structurally　characterized.　PCN-530　is　among　the　few　examples　of　metal-organic　frameworks　that　utilize　adenine　as　a　constructional　unit,　while　TMOP-1　is　the　first　existing　example　of　a　crystallographically　characterized　nucleobase-incorporated　metal-organic　polyhedron.　This　work　also　offers　a　general　perspective　for　the　design　and　synthesis　of　nucleobase-incorporated　metal-organic　materials.