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The development of lead-free dielectric ceramics with temperature insensitive high discharge energy density (W-dis) and high energy efficiency (n) are highly demanded for the practical applications in energy storage capacitors. In this work, we have designed and fabricated the NaNbO3 modified Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3 (NBT-KBT-xNN) relaxor ferroelectrics. The addition of metastable antiferroelectric NN into the NBT-KBT matrix leads to enhanced relaxor behavior and improved breakdown strength. As a result, the x = 0.4NN specimen not only showed optimal inte7grated energy storage properties with a large W-dis of 1.7 J/cm(3) and eta of 90% under a moderate electric field of 150 kV/cm, but also exhibited superior temperature stability with the variation of W-dis within +/- 15% and eta more than 80% from -50 degrees C to 150 degrees C. All these properties indicate that NN modified NBT-KBT ceramic was a promising candidate for the practical application of energy storage capacitors. (C) 2020 Elsevier B.V. All rights reserved.
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