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作者:

Zhang, Xizhu (Zhang, Xizhu.) | Wang, Jinshu (Wang, Jinshu.) (学者:王金淑) | Liu, Wei (Liu, Wei.) | Tian, Tian (Tian, Tian.) | Zhou, Meiling (Zhou, Meiling.)

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EI Scopus SCIE

摘要:

Sub-micrometer Sc2O3-W powder with a narrow particle size distribution has been obtained by a sol-gel method combined with two-step hydrogen reduction process. Based on the obtained powder, the W-Sc2O3 targets have been sintered via spark plasma sintering (SPS) at 1300 degrees C. The W-Sc2O3 targets have the average grain size of about 1 pm. Both the sintering temperature and holding time are much lower than those of the targets prepared with micrometer sized powders. The obtained W-Sc2O3 targets have a high comparative density of 96.4% and rockwell hardness of 86.4 HRC. Using the target, the scandate cathode deposited with a film containing 5% Sc2O3 and 95% W has been obtained by pulsed laser deposition (PLD) method. This cathode has good emission property, i.e., the highest thermionic emission current density reaches 43.09 A/cm(2) of idly at 900 Cb after being activated for 8 h, which is much higher than that of scandate cathode without film. Scandium (Sc) supplied by the film on the surface during the activation forms a Ba-Sc-O active layer, which helps to the emission. (C) 2013 Elsevier Ltd. All rights reserved.

关键词:

Electrical properties Laser deposition Nanostructures Sol-gel chemistry

作者机构:

  • [ 1 ] [Zhang, Xizhu]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab New Funct Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Jinshu]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab New Funct Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Wei]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab New Funct Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Tian, Tian]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab New Funct Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Zhou, Meiling]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab New Funct Mat, Beijing 100124, Peoples R China

通讯作者信息:

  • 王金淑

    [Wang, Jinshu]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab New Funct Mat, Beijing 100124, Peoples R China

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来源 :

MATERIALS RESEARCH BULLETIN

ISSN: 0025-5408

年份: 2013

期: 12

卷: 48

页码: 5040-5044

5 . 4 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:263

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 10

SCOPUS被引频次: 11

ESI高被引论文在榜: 0 展开所有

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