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作者:

Yue, Yonghai (Yue, Yonghai.) | Chen, Nianke (Chen, Nianke.) | Li, Xianbin (Li, Xianbin.) | Zhang, Shengbai (Zhang, Shengbai.) | Zhang, Ze (Zhang, Ze.) | Chen, Mingwei (Chen, Mingwei.) | Han, Xiaodong (Han, Xiaodong.) (学者:韩晓东)

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摘要:

Via in situ TEM tensile tests on single crystalline copper nanowires with an advanced tensile device, we report here a crystalline-liquid-rubber-like (CRYS-LIQUE-R) behavior in fracturing crystalline metallic nanowires. A retractable strain of the fractured crystalline Cu nanowires can approach over 35%. This astonishing CRYS-LIQUE-R behavior of the fracturing highly strained single crystalline Cu nanowires originates from an instant release of the stored ultralarge elastic energy in the crystalline nanowires. The release of the ultralarge elastic energy was estimated to generate a huge reverse stress as high as similar to 10 GPa. The effective diffusion coefficient (D-eff) increased sharply due to the consequent pressure gradient. In addition, due to the release of ultrahigh elastic energy, the estimated concomitant temperature increase was estimated as high as 0.6 Tm (Tm is the melting point of nanocrystalline Cu) on the fractured tip of the nanowires. These factors greatly enhanced the atomic diffusion process. Molecular dynamic simulations revealed that the very high reverse stress triggered dislocation nucleation and exhaustion.

关键词:

Crystalline-liquid-rubber (CRYS-LIQUE-R) large retractable strain in situ TEM single crystalline Cu pressure gradient effective diffusion nanowires

作者机构:

  • [ 1 ] [Yue, Yonghai]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Ze]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Han, Xiaodong]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Xianbin]Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
  • [ 5 ] [Zhang, Shengbai]Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
  • [ 6 ] [Zhang, Shengbai]Rensselaer Polytech Inst, Dept Phys Appl Phys & Astron, Troy, NY 12180 USA
  • [ 7 ] [Zhang, Ze]ZheJiang Univ, Dept Mat Sci, State Key Lab Si Mat, Hangzhou 310058, Zhejiang, Peoples R China
  • [ 8 ] [Chen, Mingwei]Tohoku Univ, WPI Adv Inst Mat Res, Sendai, Miyagi 9808577, Japan
  • [ 9 ] [Yue, Yonghai]Beihang Univ, Sch Chem & Environm, Beijing 100191, Peoples R China

通讯作者信息:

  • [Zhang, Shengbai]Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China

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来源 :

NANO LETTERS

ISSN: 1530-6984

年份: 2013

期: 8

卷: 13

页码: 3812-3816

1 0 . 8 0 0

JCR@2022

ESI学科: PHYSICS;

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 45

SCOPUS被引频次: 44

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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