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作者:

Zubair, Muhammad (Zubair, Muhammad.) | Wang, Errui (Wang, Errui.) | Wang, Yinzhong (Wang, Yinzhong.) | Wang, Boya (Wang, Boya.) | Wang, Lin (Wang, Lin.) | Liang, Yuan (Liang, Yuan.) | Yu, Haijun (Yu, Haijun.) (学者:尉海军)

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EI Scopus SCIE CSCD

摘要:

The voltage decay of lithium-rich layered oxides (LLOs) is still one of the key challenges for their application in commercial battery although these materials possess the advantages of high specific capacity and low cost. In this work, the relationship between voltage decay and tap density of LLOs has been focused. The voltage decay can be significantly suppressed with the increasing tap density as well as the homogenization of the primary or secondary particle size of agglomerated spherical LLOs. Experimental results have shown that an extreme small voltage decay of 0.98 mV cycle(-1) can be obtained through adjusting the tap density of agglomerated spherical LLOs to 1.99 g cm(-3), in which the size of primary and secondary particles are uniform. Our work offers a new insight towards the voltage decay and capacity fading of LLOs through precursor preparation process, promoting their application in the real battery in the future. (C) 2020 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

关键词:

Cycle stability Lithium-rich layered oxides Tap density Voltage decay Agglomerated spherical particle

作者机构:

  • [ 1 ] [Zubair, Muhammad]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Errui]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Yinzhong]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Boya]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Lin]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 6 ] [Liang, Yuan]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 7 ] [Yu, Haijun]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China

通讯作者信息:

  • 尉海军

    [Yu, Haijun]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY

ISSN: 1005-0302

年份: 2020

卷: 58

页码: 107-113

1 0 . 9 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:169

被引次数:

WoS核心集被引频次: 9

SCOPUS被引频次: 11

ESI高被引论文在榜: 0 展开所有

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