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作者:

Deng Xiaojun (Deng Xiaojun.) | Liu Danming (Liu Danming.) (学者:刘丹敏) | Yue Ming (Yue Ming.) (学者:岳明) | Huang Qingzhen (Huang Qingzhen.) | Zhao Jinliang (Zhao Jinliang.) | Zhang Jiuxing (Zhang Jiuxing.)

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EI Scopus SCIE PKU CSCD

摘要:

Mn1.1Fe0.9P0.8Ge0.2Bx (x=0, 0.02, 0.03, 0.04) compounds were prepared by mechanical milling and subsequent spark plasma sintering (SPS) technique. Their crystal structure was investigated by XRD and the magneticaloric properties were measured by DSC and VSM. Results show that Mn1.1Fe0.9P0.8Ge0.2Bx (x=0, 0.02, 0.03, 0.04) compounds possess a hexagonal Fe2P-type crystal structure. The lattice parameters a and c are changed noticeably with the increase of B, and c/a ratio decreases firstly and then increases. There is a nonlinear relationship between Curie temperature as well as the entropy change and the content of B. The compound achieves the best magneticaloric properties in this system when x=0.02. The Curie temperature increases from 253 K for x=0 to 263 K, and thermal hysteresis decreases from 23 K to 19 K. The maximum value of the magnetic entropy change increases from 28.7 to 32.6 J/kg.K for a field change from 0 to 2 T.

关键词:

magneticaloric effect MnFePGeB room temperature magnetic refrigerant

作者机构:

  • [ 1 ] [Deng Xiaojun]Beijing Univ Technol, Beijing 100124, Peoples R China
  • [ 2 ] [Liu Danming]Beijing Univ Technol, Beijing 100124, Peoples R China
  • [ 3 ] [Yue Ming]Beijing Univ Technol, Beijing 100124, Peoples R China
  • [ 4 ] [Zhao Jinliang]Beijing Univ Technol, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Jiuxing]Beijing Univ Technol, Beijing 100124, Peoples R China
  • [ 6 ] [Huang Qingzhen]NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA

通讯作者信息:

  • 刘丹敏

    [Liu Danming]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China

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来源 :

RARE METAL MATERIALS AND ENGINEERING

ISSN: 1002-185X

年份: 2013

期: 7

卷: 42

页码: 1450-1453

0 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:263

JCR分区:4

中科院分区:4

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WoS核心集被引频次: 2

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