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作者:

Zhang Meng (Zhang Meng.) | Liu Danmin (Liu Danmin.) (学者:刘丹敏) | Liu Cuixiu (Liu Cuixiu.) | Huang Qingzhen (Huang Qingzhen.) | Wang Shaobo (Wang Shaobo.) | Zhang Hu (Zhang Hu.) | Yue Ming (Yue Ming.) (学者:岳明)

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EI Scopus SCIE PKU CSCD

摘要:

In recent years, the MnFePGe compound has drawn tremendous attention not only for its excellent magnetocaloric effect (MCE), but also for its great commercial interest. Compared with other advanced MCE materials such as GdSiGe, MnFePAs, etc., it possesses many practical advantages such as more abundant raw materials, lower fabrication costs as well as better environmental amity. In this work, Mn1.2Fe0.8P0.76Ge0.24 compound was prepared by mechanical milling and subsequent spark plasma sintering (SPS) technique, its microstructure was investigated by SEM, meanwhile the relationship between phase transition and the properties was investigated by neutron diffraction, SQUID, DSC and XRD. The results show that the Mn1.2Fe0.8P0.76Ge0.24 compound is compact, and possess a hexagonal Fe2P-type crystal structure. Generally, either applied magnetic field or temperature change will induce the transformation between paramagnetic phase and ferromagnetic phase. When the applied magnetic field increased or temperature reduced, paramagnetic phase transformed to ferromagnetic phase and caused the magnetic entropy change to become larger. It is found that the magnetic entropy change of Mn1.2Fe0.8P0.76Ge0.24 compound is directly corresponding to the percentage of the phase transition.

关键词:

magnetic thermal phase transition process neutron diffraction magnetic refrigeration material

作者机构:

  • [ 1 ] [Zhang Meng]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Liu Danmin]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Liu Cuixiu]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Wang Shaobo]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Hu]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Huang Qingzhen]NIST, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA
  • [ 7 ] [Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 刘丹敏

    [Liu Danmin]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China

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来源 :

ACTA METALLURGICA SINICA

ISSN: 0412-1961

年份: 2013

期: 7

卷: 49

页码: 783-788

2 . 3 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

JCR分区:3

中科院分区:4

被引次数:

WoS核心集被引频次: 5

SCOPUS被引频次: 4

ESI高被引论文在榜: 0 展开所有

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