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摘要:
In this study, we discussed an efficient approach for the synthesis of camphorquinone from camphor by the continuous reaction of bromination and oxidation. The oxidation of 3-bromocamphor was catalyzed by Fe-porphyrins with air. The catalytic activity of iron-metallated functional porphyrins was investigated under optimization conditions. The results showed that this method was a milder alternative to the reported methods, with a simple, greener procedure in which the advantages were the utilization of air as the oxidant and the use of metalloporphyrins as catalysts.
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来源 :
SYNTHETIC COMMUNICATIONS
ISSN: 0039-7911
年份: 2013
期: 11
卷: 43
页码: 1543-1548
2 . 1 0 0
JCR@2022
ESI学科: CHEMISTRY;
JCR分区:3
中科院分区:4