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摘要:
Crystal structure, and thermal and magnetic properties have been studied for bulk MnFePSiGe compounds with different silicon contents prepared by the spark plasma sintering method. The MnFePSiGe compounds crystallize in a hexagonal Fe2P-type structure without obvious secondary phase. The compounds undergo a ferromagnetic to paramagnetic first-order transition near their Curie temperature (T-c). With increase of Si content, both T-c and magnetic entropy change (-Delta S-M) of the compounds rise remarkably, while the thermal hysteresis (T-hys) remains almost invariant. For MnFeP0.63Si0.26Ge0.11 compound, the T-c and -Delta S-M for a magnetic field change from 0 to 2 T are 318 K and 27.9 J/Kg K, respectively, and its phase transition entropy change (Delta S) obtained from DSC is 32.3 J/Kg K. (C) 2013 Elsevier B.V. All rights reserved.
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来源 :
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
ISSN: 0304-8853
年份: 2013
卷: 335
页码: 114-117
2 . 7 0 0
JCR@2022
ESI学科: PHYSICS;
JCR分区:2
中科院分区:3