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作者:

Wang, B. B. (Wang, B. B..) | Zheng, K. (Zheng, K..) (学者:郑坤) | Shao, R. W. (Shao, R. W..)

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EI Scopus SCIE

摘要:

The catalyst-free growth of carbon nanotips and nanotubes on silicon substrate pre-deposited with carbon film was realized under different temperatures in plasma-enhanced hot filament chemical vapor deposition system, in which methane, nitrogen and hydrogen were used as the reactive gases. The structure and composition of synthesized carbon nanotips and nanotubes were investigated using field emission scanning electron microscope, transmission electron microscope and micro-Raman spectroscopy, respectively. The results indicate that the carbon nanotips are formed at about 800 degrees C while the carbon nanotubes are formed about 900 degrees C. According to the ion bombardment effect and the diffusion at different temperatures, the catalyst-free formation of carbon nanotips and nanotubes was comparatively studied. The transformation from carbon film to spherical carbon particles at a high temperature results in the formation of carbon nanotubes depending on the diffusion of carbon. At a low temperature, the carbon film still locates at the substrate and leads to the formation of carbon nanotips relying on the sputtering-etching of etching ions and the deposition of carbonaceous ions. In addition, the electron field emission characteristics of carbon nanotips and nanotubes were investigated. The results indicate that there is much difference in the electron field emission properties for the carbon nanotips and nanotubes. According to the thermal effect produced by Joule heat during electron emission, the difference was interpreted. (C) 2013 Elsevier B.V. All rights reserved.

关键词:

Thermal effect Carbon nanotubes Diffusion Temperature Carbon nanotips

作者机构:

  • [ 1 ] [Wang, B. B.]Chongqing Univ Technol, Coll Chem & Chem Engn, Chongqing 400054, Peoples R China
  • [ 2 ] [Zheng, K.]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Shao, R. W.]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China

通讯作者信息:

  • [Wang, B. B.]Chongqing Univ Technol, Coll Chem & Chem Engn, 69 Hongguang Rd, Chongqing 400054, Peoples R China

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来源 :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

年份: 2013

卷: 273

页码: 268-272

6 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

JCR分区:1

中科院分区:2

被引次数:

WoS核心集被引频次: 1

SCOPUS被引频次: 3

ESI高被引论文在榜: 0 展开所有

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