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作者:

Li, Ruina (Li, Ruina.) | Wang, Lili (Wang, Lili.) | Gao, Xiaotong (Gao, Xiaotong.) | Du, Gangfeng (Du, Gangfeng.) | Zhai, Honglin (Zhai, Honglin.) | Wang, Xiayan (Wang, Xiayan.) | Guo, Guangsheng (Guo, Guangsheng.) | Pu, Qiaosheng (Pu, Qiaosheng.)

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EI Scopus SCIE

摘要:

Rapid analysis of trace amount of aromatic amines in environmental samples and daily necessities has attracted considerable attentions because some of them are strongly toxic and carcinogenic. In this study, fast and efficient electrophoretic separation and sensitive determination of 5 banned aromatic amines were explored for practical analysis using disposable plastic microchips combined with a low-cost laser-induced fluorescence detector. The effect of running buffer and its additive was systematically investigated. Under the selected condition, 5 fluorescein isothiocyanate labeled aromatic amines could be baseline separated within 90s by using a 10 mmol/L borate buffer containing 2% (w/v) hydroxypropyl cellulose. Calibration curves of peak areas vs. concentrations were linear up to 40 or 120 mu mol/L for different analytes and limits of detection were in a range of 1-3 nmol/L. Theoretical plate numbers of 6.8-8.5 x 10(5)/m were readily achieved. The method exhibited good repeatability, relative standard deviations (n=5) of peak areas and migration times were no more than 4.6% and 0.9%, respectively. The established method was successfully applied in the quantitative analysis of these banned aromatic amines in real samples of waste water and textile, recoveries of added standards were 85-110%. (C) 2013 Elsevier B.V. All rights reserved.

关键词:

Aromatic amine Cyclic olefin copolymer Laser-induced fluorescence Microchip electrophoresis Microfluidics

作者机构:

  • [ 1 ] [Li, Ruina]Lanzhou Univ, Dept Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
  • [ 2 ] [Wang, Lili]Lanzhou Univ, Dept Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
  • [ 3 ] [Gao, Xiaotong]Lanzhou Univ, Dept Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
  • [ 4 ] [Du, Gangfeng]Lanzhou Univ, Dept Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
  • [ 5 ] [Zhai, Honglin]Lanzhou Univ, Dept Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
  • [ 6 ] [Pu, Qiaosheng]Lanzhou Univ, Dept Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
  • [ 7 ] [Wang, Xiayan]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Guo, Guangsheng]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Pu, Qiaosheng]Lanzhou Univ, Dept Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

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来源 :

JOURNAL OF HAZARDOUS MATERIALS

ISSN: 0304-3894

年份: 2013

卷: 248

页码: 268-275

1 3 . 6 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:131

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 22

SCOPUS被引频次: 23

ESI高被引论文在榜: 0 展开所有

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