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Author:

Hou, Junxian (Hou, Junxian.) | Liu, Zhongliang (Liu, Zhongliang.) (Scholars:刘中良) | Zhang, Peiyuan (Zhang, Peiyuan.)

Indexed by:

EI Scopus SCIE

Abstract:

A novel microbial fuel cell (MFC) anode is fabricated by electrochemically reducing graphene oxide (ERGNO) first and coating polyaniline (PANI) nano-fibers afterward on the surface of carbon cloth (CC). ERGNO/CC is prepared using an electrochemical synthesis method reducing graphene oxide by cyclic voltammetry (CV) in phosphate buffer solution (PBS, pH = 6.9). Combining the advantages of PANI and ERGNO, PANI-ERGNO/CC yields a maximum power density of 1390 mW m(-2) when used as the MFC anode, which is 3 times larger than that of the MFC with the CC anode. The electrodes are characterized by scanning electron microscopy (SEM) and Raman spectroscopy. The electrochemical activities have been investigated by CV and electrochemical impedance spectroscopy (EIS). The great improvement is attributed to the fact that graphene not only serves as a highly conductive support material, but also provides large surface for PANI. High conductivity and large specific surface area greatly improve the charge transfer efficiency and the bacterial biofilm loading. In this work, a practical and promising synthesis method is developed to fabricate high-performance MFC anodes. (C) 2012 Elsevier B.V. All rights reserved.

Keyword:

Graphene nano-sheets Microbial fuel cell Electrochemically reducing graphene oxide Polyaniline nano-fibers Electrode modification

Author Community:

  • [ 1 ] [Liu, Zhongliang]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Zhongliang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Educ Commiss, Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 刘中良

    [Liu, Zhongliang]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2013

Volume: 224

Page: 139-144

9 . 2 0 0

JCR@2022

ESI Discipline: ENGINEERING;

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 243

SCOPUS Cited Count: 306

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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