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作者:

Wang, B. B. (Wang, B. B..) | Ostrikov, K. (Ostrikov, K..) | van der Laan, T. (van der Laan, T..) | Zheng, K. (Zheng, K..) (学者:郑坤) | Wang, J. J. (Wang, J. J..) | Yan, Y. P. (Yan, Y. P..) | Quan, X. J. (Quan, X. J..)

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EI Scopus SCIE

摘要:

Carbon nanorods and graphene-like nanosheets are catalytically synthesized in a hot filament chemical vapor deposition system with and without plasma enhancement, with gold used as a catalyst. The morphological and structural properties of the carbon nanorods and nanosheets are investigated by field-emission scanning electron microscopy, transmission electron microscopy and micro-Raman spectroscopy. It is found that carbon nanorods are formed when a CH4 + H-2 + N-2 plasma is present while carbon nanosheets are formed in a methane environment without a plasma. The formation of carbon nanorods and carbon nanosheets are analyzed. The results suggest that the formation of carbon nanorods is primarily a precipitation process while the formation of carbon nanosheets is a complex process involving surface-catalysis, surface diffusion and precipitation influenced by the Gibbs-Thomson effect. The electron field emission properties of the carbon nanorods and graphene-like nanosheets are measured under high-vacuum; it is found that the carbon nanosheets have a lower field emission turn-on than the carbon nanorods. These results are important to improve the understanding of formation mechanisms of carbon nanomaterials and contribute to eventual applications of these structures in nanodevices.

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作者机构:

  • [ 1 ] [Wang, B. B.]Chongqing Univ Technol, Coll Chem & Chem Engn, Chongqing 400054, Peoples R China
  • [ 2 ] [Yan, Y. P.]Chongqing Univ Technol, Coll Chem & Chem Engn, Chongqing 400054, Peoples R China
  • [ 3 ] [Quan, X. J.]Chongqing Univ Technol, Coll Chem & Chem Engn, Chongqing 400054, Peoples R China
  • [ 4 ] [Wang, B. B.]CSIRO Mat Sci & Engn, PNCA, Lindfield, NSW 2070, Australia
  • [ 5 ] [Ostrikov, K.]CSIRO Mat Sci & Engn, PNCA, Lindfield, NSW 2070, Australia
  • [ 6 ] [van der Laan, T.]CSIRO Mat Sci & Engn, PNCA, Lindfield, NSW 2070, Australia
  • [ 7 ] [Ostrikov, K.]Univ Sydney, Sch Phys, Sydney, NSW 2006, Australia
  • [ 8 ] [van der Laan, T.]Univ Sydney, Sch Phys, Sydney, NSW 2006, Australia
  • [ 9 ] [Zheng, K.]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 10 ] [Wang, J. J.]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China

通讯作者信息:

  • [Ostrikov, K.]CSIRO Mat Sci & Engn, PNCA, POB 218, Lindfield, NSW 2070, Australia

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来源 :

JOURNAL OF MATERIALS CHEMISTRY C

ISSN: 2050-7526

年份: 2013

期: 46

卷: 1

页码: 7703-7708

6 . 4 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

JCR分区:4

中科院分区:1

被引次数:

WoS核心集被引频次: 24

SCOPUS被引频次: 26

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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