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摘要:
Bulk Mn1.2Fe0.8-P0.76Ge0.24 alloy was prepared by mechanical milling and subsequent spark plasma sintering technique. Effect of annealing on the structure and magneto-caloric properties of the alloy was investigated. XRD results show that both sintered and annealed samples possess a hexagonal Fe2P-type crystal structure. After annealing, ferromagnetic impurity Fe3Mn4Ge6, which exists in the sintered sample, was eliminated from the alloy. Furthermore, the lattice constants a and c change noticeably, leading to a decrease in c/a ratio, while the cell volume almost remains invariable. As a result, the Curie temperature of the alloy increases from 253 K to 298 K, but the maximum magnetic entropy change decreases from 37.5 to 11.7 J.kg.K-1 for 2 T magnetic field change. On the other hand, the thermal hysteresis of M-T curves around T-C upon heating and cooling is 14 and 8 K for the as-sintered and the annealed sample, respectively, showing evident change.
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RARE METALS
ISSN: 1001-0521
年份: 2012
期: 4
卷: 31
页码: 336-338
8 . 8 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
JCR分区:3
中科院分区:4