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作者:

Xu Hang (Xu Hang.) | Yue Ming (Yue Ming.) (学者:岳明) | Zhao Chuan (Zhao Chuan.) | Zhang Dongtao (Zhang Dongtao.) (学者:张东涛) | Zhang Jiuxing (Zhang Jiuxing.)

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EI Scopus SCIE CSCD

摘要:

Bulk Mn1.2Fe0.8-P0.76Ge0.24 alloy was prepared by mechanical milling and subsequent spark plasma sintering technique. Effect of annealing on the structure and magneto-caloric properties of the alloy was investigated. XRD results show that both sintered and annealed samples possess a hexagonal Fe2P-type crystal structure. After annealing, ferromagnetic impurity Fe3Mn4Ge6, which exists in the sintered sample, was eliminated from the alloy. Furthermore, the lattice constants a and c change noticeably, leading to a decrease in c/a ratio, while the cell volume almost remains invariable. As a result, the Curie temperature of the alloy increases from 253 K to 298 K, but the maximum magnetic entropy change decreases from 37.5 to 11.7 J.kg.K-1 for 2 T magnetic field change. On the other hand, the thermal hysteresis of M-T curves around T-C upon heating and cooling is 14 and 8 K for the as-sintered and the annealed sample, respectively, showing evident change.

关键词:

isothermal entropy change Mn1.2Fe0.8P0.76Ge0.24 thermal hysteresis lattice constants

作者机构:

  • [ 1 ] [Xu Hang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zhao Chuan]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang Dongtao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Jiuxing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 岳明

    [Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

RARE METALS

ISSN: 1001-0521

年份: 2012

期: 4

卷: 31

页码: 336-338

8 . 8 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

JCR分区:3

中科院分区:4

被引次数:

WoS核心集被引频次: 9

SCOPUS被引频次: 9

ESI高被引论文在榜: 0 展开所有

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