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作者:

Han Zhi-Ming (Han Zhi-Ming.) | Zhang Xin (Zhang Xin.) | Lu Qing-Mei (Lu Qing-Mei.) | Zhang Jiu-Xing (Zhang Jiu-Xing.) | Zhang Fei-Peng (Zhang Fei-Peng.)

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EI Scopus SCIE PKU CSCD

摘要:

n-type (Mg2Si1-xSbx)(0.4)-(Mg2Sn)(0.6) (0 <= x <= 0.0625) alloys were prepared by an induction melting and spark plasma sintering method using bulks of Mn, Si, Sn, Sb as raw materials. The analyzing results of the structure and thermoelectric properties show that the single-phase (Mg2Si1-xSbx)(0.4)-(Mg2Sn)(0.6) alloys can be obtained at 8wt% excess of Mg addition. The lattice constant increases linearly with the amount of Sb, the electrical resistivity rho firstly increases and then decreases. The electrical resistivity rho of samples (x <= 0.025) shows semi-conductor behavior, while that of the samples (x>0.025) shows the metallic behavior. The Seebeck coefficient alpha firstly increases and then decreases with the increase of x value. Compared with the non-doped sample, the thermal conductivity kappa for samples (x <= 0.025) decreases and that of the other samples (x>0.025) increases. The ZT value for (Mg2Si0.95Sb0.05)(0.4)-(Mg2Sn)(0.6) sample reaches its highest value of 1.22 at 773 K, which is much higher than that of the non-doped sample.

关键词:

Mg2Si base thermoelectric materials Sb doping spark plasma sintering thermoelectric properties

作者机构:

  • [ 1 ] [Han Zhi-Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang Xin]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Lu Qing-Mei]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang Jiu-Xing]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Fei-Peng]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

通讯作者信息:

  • [Han Zhi-Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF INORGANIC MATERIALS

ISSN: 1000-324X

年份: 2012

期: 8

卷: 27

页码: 822-826

1 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:294

JCR分区:3

中科院分区:4

被引次数:

WoS核心集被引频次: 5

SCOPUS被引频次: 5

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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