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作者:

Ye, Qing (Ye, Qing.) (学者:叶青) | Yan, Lina (Yan, Lina.) | Wang, Haiping (Wang, Haiping.) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (学者:程水源) | Wang, Dao (Wang, Dao.) | Kang, Tianfang (Kang, Tianfang.) (学者:康天放) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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EI Scopus SCIE

摘要:

The undoped and rare earth oxide (REOx, RE = La, Ce, Pr, Sm)-doped acid-treated sepiolite (H-Sep)-supported copper oxide catalysts (Cu/H-Sep and RE-Cu/H-Sep: Cu and RE loading = 15 and 4 wt%, respectively) were prepared using the incipient wetness impregnation method. The catalysts were characterized by means of the XRD, BET, XPS, H-2-TPR and NH3-TPD techniques, and their catalytic activities were evaluated for the selective catalytic reduction (SCR) of NO with propylene. It is shown that the doping of REOx led to an enhancement in catalytic performance of Cu/H-Sep in the SCR of NO with C3H6. Among the RE-Cu/H-Sep catalysts, Ce-Cu/H-Sep performed the best, with 62% NO conversion being achieved at 350 degrees C in the (NO + C3H6 + O-2) reaction. We believe that the high catalytic performance of Ce-Cu/H-Sep for the SCR of NO with C3H6 was associated with the good low-temperature reducibility, high copper oxide dispersion, and strong metal-support interaction. (c) 2012 Elsevier B.V. All rights reserved.

关键词:

Selective catalytic reduction Metal-support interaction Sepiolite-supported copper oxide catalyst NO removal Rare earth oxide dopant

作者机构:

  • [ 1 ] [Ye, Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Yan, Lina]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Haiping]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Cheng, Shuiyuan]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Dao]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Kang, Tianfang]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

通讯作者信息:

  • 叶青

    [Ye, Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China

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来源 :

APPLIED CATALYSIS A-GENERAL

ISSN: 0926-860X

年份: 2012

卷: 431

页码: 42-48

5 . 5 0 0

JCR@2022

ESI学科: CHEMISTRY;

JCR分区:1

中科院分区:2

被引次数:

WoS核心集被引频次: 32

SCOPUS被引频次: 33

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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