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作者:

Liu, Guo (Liu, Guo.) | Lu, Qingmei (Lu, Qingmei.) | Zhang, Xin (Zhang, Xin.) | Zhang, Jiuxing (Zhang, Jiuxing.) | Shi, Yongjun (Shi, Yongjun.)

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EI Scopus SCIE

摘要:

Polycrystalline Cr-doped higher manganese silicides (HMSs) Mn1- Cr Si-1.80 ( = 0 to 0.03) were prepared by the spark plasma sintering method. The phase structure and microstructure of the bulk samples were investigated, and their thermoelectric (TE) properties were measured from 473 K to 873 K. x-Ray diffraction patterns show that almost all of the Cr-doped samples possess single-phase HMS structure. However, minor amounts of MnSi phase can be observed in scanning electron microscopy images. The electrical conductivity increases continuously with increasing Cr substitution, and is enhanced by up to 15% for bulk Mn0.97Cr0.03Si1.80 over the entire measurement range from 473 K to 873 K. Meanwhile, the Seebeck coefficient is slightly depressed, so that the power factor is increased by about 10%. Cr doping affects the thermal conductivity negatively, and the overall dimensionless TE figure of merit of all the samples decreases slightly due to the higher thermal conductivity.

关键词:

thermoelectric properties Higher manganese silicides Cr doping spark plasma sintering

作者机构:

  • [ 1 ] [Liu, Guo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Lu, Qingmei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Xin]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Jiuxing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Shi, Yongjun]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Liu, Guo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF ELECTRONIC MATERIALS

ISSN: 0361-5235

年份: 2012

期: 6

卷: 41

页码: 1450-1455

2 . 1 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 15

SCOPUS被引频次: 18

ESI高被引论文在榜: 0 展开所有

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