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摘要:
BiAlO3 is a perovskite ferroelectric with a high Curie temperature above 520A degrees C. However, it is difficult to prepare pure perovskite phase by the conventional method. In this experiment, BaTiO3 has been selected as host to incorporate BiAlO3, and the nominal binary system of (1-x)BaTiO3-xBiAlO(3) has been investigated with regard to its Curie temperature (T (c)) and dielectric relax behaviors. It was found that the pure perovskite phase can be retained below x = 0.08. However, the value of T (c) in the system doesn't follow the normal Vegard's law, on the contrary, shows the decreasing trend with the increase of x. According to the compared experiments about Bi3+ and Al3+ doping in BaTiO3, it can be safely concluded that the combined substitution of Bi3+ and Al3+ played the dominant role to decrease the T (c) and increase the relaxor behavior in (1-x)BaTiO3-xBiAlO(3) system.
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来源 :
JOURNAL OF ELECTROCERAMICS
ISSN: 1385-3449
年份: 2012
期: 2-3
卷: 28
页码: 105-108
1 . 7 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:294
JCR分区:2
中科院分区:3