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作者:

Ye Qing (Ye Qing.) (学者:叶青) | Huo Fei-Fei (Huo Fei-Fei.) | Yan Li-Na (Yan Li-Na.) | Wang Juan (Wang Juan.) | Cheng Shui-Yuan (Cheng Shui-Yuan.) (学者:程水源) | Kang Tian-Fang (Kang Tian-Fang.) (学者:康天放)

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Scopus SCIE PKU CSCD

摘要:

alpha-MnO2-supported gold catalysts (xAu/alpha-MnO2, x=0-7 (corresponding to the Au loading (mass fraction) of 0-7%) were prepared by a deposition- precipitation method using urea as a precipitation agent and characterized by different techniques such as X-ray diffraction (XRD), N-2 adsorption-desorption measurements, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and H-2 temperature-programmed reduction (TPR). The catalytic activities of the materials were evaluated for the oxidation of CO and benzene. The Au particle size was found to be related to the Au loading of the xAu/alpha-MnO2 samples and increased with Au loading. XPS results showed that the mole ratios of O2-/(O-2(2-) or O-), Mn4+/Mn3+ and Au3+/Au-0 increased upon the addition of Au. The loading of gold over alpha-MnO2 significantly modified the catalytic activities. The catalytic performance of xAu/alpha-MnO2 strongly depended on the Au loading, and 3Au/alpha-MnO2 gained the best activity at T(90=)80 degrees C and T-90=20 degrees C for the catalytic oxidation of CO and benzene, respectively. The excellent performance of 3Au/alpha-MnO2 is associated with highly dispersed Au, good low-temperature reducibility, and a synergism at the interface between the Au and MnO2 nanodomains.

关键词:

Carbon monoxide oxidation Low-temperature reducibility alpha-MnO2 supported gold catalyst Synergistic action Benzene combustion

作者机构:

  • [ 1 ] [Ye Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Huo Fei-Fei]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Yan Li-Na]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Wang Juan]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Cheng Shui-Yuan]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Kang Tian-Fang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 叶青

    [Ye Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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来源 :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

年份: 2011

期: 12

卷: 27

页码: 2872-2880

1 0 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

JCR分区:4

中科院分区:4

被引次数:

WoS核心集被引频次: 8

SCOPUS被引频次: 11

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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