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作者:

Li, Chuan-Qiang (Li, Chuan-Qiang.) | Qiu, Wen-Ge (Qiu, Wen-Ge.) (学者:邱文革) | He, Hong (He, Hong.) (学者:何洪)

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摘要:

In the crystal structure of the title coordination polymer, {[Zn-2(C17H8O10)(C3H7NO)(2)]center dot C3H7NO}(n), the molecular building block (MBB), viz. {Zn-2(CO2)(4)(C3H7NO)(2)}, comprises two zinc atoms, each bridged by three carboxylate groups. These two Zn atoms exhibit different coordination environments: a distorted coordination intermediate between trigonal-pyramidal, and square-pyramidal formed by the two coordinated dimethylformamide molecules and three carboxylate groups, and a distorted tetrahedral coordination defined by carboxylate groups of which three are bidentate bridging and the fourth is a monodentate ligand. Thus, each ligand connects four MBBs, forming the three-dimensional polymer.

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作者机构:

  • [ 1 ] [Li, Chuan-Qiang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Qiu, Wen-Ge]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [He, Hong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 邱文革

    [Qiu, Wen-Ge]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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来源 :

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

ISSN: 2056-9890

年份: 2011

卷: 67

页码: M1406-U1018

0 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

被引次数:

WoS核心集被引频次: 1

SCOPUS被引频次: 1

ESI高被引论文在榜: 0 展开所有

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