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作者:

Liu, W. Q. (Liu, W. Q..) (学者:刘卫强) | Cui, Z. Z. (Cui, Z. Z..) | Wang, G. P. (Wang, G. P..) | Zhang, D. T. (Zhang, D. T..) (学者:张东涛) | Yue, M. (Yue, M..) (学者:岳明) | Zhang, J. X. (Zhang, J. X..)

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EI Scopus SCIE

摘要:

Static state immersion experiments, polarisation curve and electrochemical impedance spectroscopy tests have been applied to investigate the corrosion kinetics for both spark plasma sintered (SPS) and conventional sintered Nd-Fe-B magnets in NaCl electrolyte. Effect of microstructure modification on their chemical stability of the magnets was discussed. The electrochemical reactions of both magnets are controlled by the step of active substances adsorption process at the open circuit potential and the anodic potential, which turn to diffusion process at the cathodal potential. Although both magnets are susceptible to corrosion in saline electrolytes, SPS magnets are more corrosion resistant than conventional sintered magnets due to their special microstructure that is different from those of conventional sintered magnets. In SPS magnets, the grain size of the Nd(2)Fe(14)B main phase is fine and uniform, only a few Nd rich phase form along the grain boundaries of Nd(2)Fe(14)B phase, while most of them agglomerate into triple junctions as small particles. Such microstructure effectively restrains the aggressive intergranular corrosion along Nd rich phases. As a result, the SPS magnet possesses excellent corrosion resistance in NaCl electrolyte.

关键词:

Corrosion kinetics Microstructure modification Nd-Fe-B permanent magnets Spark plasma sintering

作者机构:

  • [ 1 ] [Liu, W. Q.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Cui, Z. Z.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, D. T.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Yue, M.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, J. X.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, G. P.]Jiangxi Normal Univ, Coll Phys & Commun Elect, Nanchang 330022, Peoples R China

通讯作者信息:

  • 岳明

    [Yue, M.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

CORROSION ENGINEERING SCIENCE AND TECHNOLOGY

ISSN: 1478-422X

年份: 2011

期: 5

卷: 46

页码: 667-670

1 . 8 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:290

JCR分区:2

中科院分区:4

被引次数:

WoS核心集被引频次: 3

SCOPUS被引频次: 3

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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