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作者:

Li, Shuaishuai (Li, Shuaishuai.) | Zeng, Wei (Zeng, Wei.) (学者:曾薇) | Jia, Ziyue (Jia, Ziyue.) | Wu, Guoding (Wu, Guoding.) | Xu, Huanhuan (Xu, Huanhuan.) | Peng, Yongzhen (Peng, Yongzhen.) (学者:彭永臻)

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EI Scopus SCIE

摘要:

Phosphorus recovery from sewage sludge is necessary to promote the sustainable recovery of agricultural fertilizer products and prevent the negative environmental problems. In this study, an innovation procedure of FeCl3-assisted sewage sludge hydrothermal carbonization (HTC) treatment for selective elution of apatite phosphorus (AP) has been developed to recover phosphorus as K-struvite. AP of above 88% was eluted from the sludge solid phase at pH of 2.5, and the dissolved phosphate from AP was mainly fixed by FeCl3. The transformation of phosphorus fractions under different HTC temperature (200-260 degrees C) and time (0.5-4 h) with or without FeCl3 were subsequently investigated. Phosphorus-31 nuclear magnetic resonance (P-31 NMR) results showed that prolonging HTC time and increasing HTC temperature could disintegrate organic phosphorus (OP), while higher HTC temperature was effective for decomposition of pyrophosphate (Pyro-P). The content of orthophosphate (Ortho-P) in hydrochar accounted for above 95% of total phosphorus (TP) under HTC temperature of 200 degrees C for 4 h with FeCl3. The phosphate desorption behavior of hydrochar with FeCl3 treated was well described by Pseudo-second-order kinetic model, while the hydrochar without FeCl3 treated followed Pseudo second-order and Elovich kinetic models. About 96.1% of phosphate was extracted from the hydrochar under pH of 12.0 and contact time of 120 min. Finally, about 92.6% of TP in sewage sludge was recovered as K-struvite to alleviate the depletion of phosphorus resource.

关键词:

Elution of apatite phosphorus Hydrothermal carbonization FeCl3-assisted K-struvite Phosphorus transfer

作者机构:

  • [ 1 ] [Li, Shuaishuai]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Beijing 100124, Peoples R China
  • [ 2 ] [Zeng, Wei]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Beijing 100124, Peoples R China
  • [ 3 ] [Jia, Ziyue]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Guoding]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Beijing 100124, Peoples R China
  • [ 5 ] [Xu, Huanhuan]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Beijing 100124, Peoples R China
  • [ 6 ] [Peng, Yongzhen]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Beijing 100124, Peoples R China

通讯作者信息:

  • 曾薇

    [Zeng, Wei]Beijing Univ Technol, Dept Environm Engn, Pingleyuan 100, Beijing 100124, Peoples R China

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来源 :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

年份: 2020

卷: 399

1 5 . 1 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:115

被引次数:

WoS核心集被引频次: 55

SCOPUS被引频次: 64

ESI高被引论文在榜: 0 展开所有

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