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作者:

Chen Sha (Chen Sha.) (学者:陈莎) | Zhong Yi-Sheng (Zhong Yi-Sheng.) | Cheng Shui-Yuan (Cheng Shui-Yuan.) (学者:程水源) | Qian Tian (Qian Tian.) | Sun Hao (Sun Hao.)

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摘要:

Ionic liquid-based dispersive liquid-liquid micro-extraction (IL-DLLME) was coupled with high-performance liquid chromatography-ultraviolet (HPLC-UV) for the determination of four phthalate esters, including butyl benzyl phthalate, di-n-butyl phthalate, dicyclohexyl phthalate and bis(2-ethylhexyl) phthalate in water samples. The mixture of ionic liquid (IL) and dispersive solvent was rapidly injected into 10 mL aqueous sample. Then, IL phase was separated by centrifugation and was determined by high-performance liquid chromatography-ultraviolet. The factors influencing the extraction efficiency, such as type and volume of IL, disperse solvent, extraction time, centrifuging time and ionic strength, were investigated and optimized. Under the optimized conditions, the extraction recoveries by the proposed ionic liquid-based dispersive liquid-liquid micro-extraction for the four phthalates ranged from 83.0 to 91.7%. The relative standard deviations were between 7.8 and 15%. The limits of quantification for four phthalates were between 10.6 and 28.5 mg/L. The proposed method was successfully applied for the analysis of PAEs in tap, lake and treated wastewater samples.

关键词:

DLLME Ionic liquid Phthalate esters

作者机构:

  • [ 1 ] [Chen Sha]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing, Peoples R China
  • [ 2 ] [Zhong Yi-Sheng]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing, Peoples R China
  • [ 3 ] [Cheng Shui-Yuan]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing, Peoples R China
  • [ 4 ] [Qian Tian]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing, Peoples R China
  • [ 5 ] [Sun Hao]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing, Peoples R China

通讯作者信息:

  • 陈莎

    [Chen Sha]Chaoyang 100, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF SEPARATION SCIENCE

ISSN: 1615-9306

年份: 2011

期: 13

卷: 34

页码: 1503-1507

3 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:252

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 54

SCOPUS被引频次: 54

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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