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Solid solutions of Pb1-xTbxTi1-xMnxO3 (0 <= x <= 0.10) were synthesized by a traditional solid state reaction and characterized by powder X-ray diffraction. The solutions crystallize in the P4mm space group at room temperature. Differential scanning calorimetry (DSC) measurements were performed to obtain phase transition temperatures (T-c) for the samples, and these were found to decrease with an increase in the amount of doped Tb and Mn. The temperature dependent dielectric constant shows a peak close to the T-c, indicating that the corresponding phase transition is a ferroelectric phase transition. Magnetic measurements indicate that a paramagnetic to antiferromagnetic phase transition occurs at 25 and 29 K for Pb1-xTbxTi1-xMnxO3 with x=0.08 and x=0.10, respectively.
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