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作者:

Ye Qing (Ye Qing.) (学者:叶青) | Zhao Jian-Sheng (Zhao Jian-Sheng.) | Li Dong-Hui (Li Dong-Hui.) | Zhao Jun (Zhao Jun.) | Cheng Shui-Yuan (Cheng Shui-Yuan.) (学者:程水源) | Kang Tian-Fang (Kang Tian-Fang.) (学者:康天放)

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Scopus SCIE PKU CSCD

摘要:

Au/SnO2 catalysts were prepared by deposition-precipitation (DP), co-precipitation (CP) and typical wet impregnation methods (IM). M(M= Pt, Pd)-promoted Au/SnO2 catalysts were prepared by the DP method. The samples were characterized by X-ray diffraction (XRD), Brunaner-Emmett-Teller (BET) adsorption, transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) techniques. The results showed that compared with CP and IM, the DP method led to a fairly uniform dispersion of gold nanoparticles with diameters less than 5 nm and larger specific surfaces for the Au/SnO2 catalyst. The Au in Au/SnO2-DP was metallic (Au-0) while in Au/SnO2-CP and Au/SnO2-IM the Au consisted of a mixture of Au-0 and Au3+. The oxidation of carbon monoxide over the Au/SnO2-DP and M-promoted Au/SnO2-DP catalysts were investigated. We observed that the Pd- or Pt-doping of Au/SnO2-DP resulted in a significant increase in performance. We conclude that the different activities of the Au/SnO2 catalysts that were prepared using different preparation methods may be attributed to the size of the Au particles and the states of gold. A remarkable improvement in catalytic activity because of Pd or Pt doping was associated with strong interactions between Pd or Pt and Au.

关键词:

Au binary catalyst Au/SnO2 Low-temperature catalytic oxidation of CO Preparation method

作者机构:

  • [ 1 ] [Ye Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Zhao Jian-Sheng]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Li Dong-Hui]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Zhao Jun]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Cheng Shui-Yuan]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Kang Tian-Fang]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China

通讯作者信息:

  • 叶青

    [Ye Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Beijing 100124, Peoples R China

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来源 :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

年份: 2011

期: 1

卷: 27

页码: 169-176

1 0 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:252

JCR分区:4

中科院分区:4

被引次数:

WoS核心集被引频次: 6

SCOPUS被引频次:

ESI高被引论文在榜: 0 展开所有

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