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摘要:
Using in situ x-ray diffraction, we demonstrate a pressure-induced crystallization of as-deposited amorphous Ge2Sb2Te5 (a-GST) into a body-centered-cubic (bcc) solid solution at 28 GPa, and the back transformation from the bcc-GST to a-GST. A large hysteresis loop was observed, as the bcc-GST was retained until 15 GPa. Comparisons have been made, employing the x-ray data and the structural information obtained from ab initio molecular dynamics simulations, between the as-deposited a-GST and the a-GST obtained from the pressure-induced collapse of the rocksalt GST, both at a high hydrostatic pressure (20 GPa) prior to their crystallization to bcc. The results suggest that both routes have resulted in the same high-pressure amorphous state, which explains their crystallization into bcc-GST at similar pressures. (C) 2010 American Institute of Physics. [doi:10.1063/1.3493110]
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来源 :
JOURNAL OF APPLIED PHYSICS
ISSN: 0021-8979
年份: 2010
期: 8
卷: 108
3 . 2 0 0
JCR@2022
ESI学科: PHYSICS;
JCR分区:2
中科院分区:3