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摘要:
Asymmetric porous cordierite ceramic membranes were fabricated by phase inversion tape casting method. It is shown that the membranes consist of a relatively dense skin layer on the top, a sponge layer at the bottom and a finger-like layer in the middle. The membranes have a hierarchical pore structure, where macrovoids (denoted as dozens-micron-sized (DMS) pores) are present in the finger-like layer and micron-sized (MS) pores are located in the skin layer, sponge layer and the wall of macrovoids. After surface silylation by post-grafting with 1H,1H,2H,2H-perfluorodecyltriethoxysilane (FAS), the sample with a starting powder/polyethersulfone (PESf) weight ratio of 9 (M - 4) becomes hydrophobic, with a water contact angle of 150 degrees. At a NaCl concentration of 3.5 wt%, a feed rate of 18L/h and a feed temperature of 80 degrees C, the hydrophobic M - 4 membrane exhibits a water permeate flux of 22.33 kg/m(2)h, which is considerably larger than that of the membranes prepared by dry pressing method previously, and a salt rejection of 99.9%. The higher water permeate flux is attributed to the much lower transport resistance of water vapor in the membranes of the present work.
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来源 :
CERAMICS INTERNATIONAL
ISSN: 0272-8842
年份: 2020
期: 15
卷: 46
页码: 23677-23685
5 . 2 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:169