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作者:

Zhang Fei-Peng (Zhang Fei-Peng.) | Zhang Xin (Zhang Xin.) | Lu Qing-Mei (Lu Qing-Mei.) | Zhang Jin-Xing (Zhang Jin-Xing.)

收录:

Scopus SCIE PKU CSCD

摘要:

The electrical transport properties of Ca3Co4O9 could be in by doping in the Ca site. The Ca site doped Ca3-xAgxCo4O9 (x = 0-0 05) bulk samples were fabricated by citric acid sol-gel and spark plasma sintering method. The resulting samples were analyzed by X-ray power diffraction, scanning electron microscopy and electrical constant measurement The results showed that all samples were single phased, the prefered onentation was lowered by Ag doping for Ca The A (sic)= 0 03 sample exhibited highest grain orientation among doped samples, which exhibited layered microstructure. Its electrical resistivity was increased and then decreased slightly by Ag doping, but the transport mechanism was not changed. However, the doped samples exhibited high electrical resistivity caused by changed electronic structure by Ag doping for Ca The x = 0.04 sample exhibited highest electrical resistivity in the measuring temperature region with the highest value 14 6 m Omega.cm at 973 K.

关键词:

Ca3Co4O9 doping electrical transport

作者机构:

  • [ 1 ] [Zhang Fei-Peng]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang Xin]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Lu Qing-Mei]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang Jin-Xing]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

通讯作者信息:

  • [Lu Qing-Mei]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

ACTA PHYSICA SINICA

ISSN: 1000-3290

年份: 2010

期: 6

卷: 59

页码: 4211-4215

1 . 0 0 0

JCR@2022

ESI学科: PHYSICS;

JCR分区:2

中科院分区:4

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