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摘要:
Effect of homogenization of the chemical composition and crystal structure on the magnetocaloric effects have been studied for bulk Mn1.1Fe0.9P0.8Ge0.2 alloy prepared by mechanical alloying and subsequent spark plasma sintering method. After optimal homogenization treatment, the ferromagnetic impurity, Ge6Fe3Mn4 phase was completely eliminated from the alloy; furthermore, the crystal lattice constant of the MnFePGe main phase, which possesses a hexagonal Fe2P-type structure, varies obviously compared with that of the sintered sample. As a result, the Curie temperature, T-C, of the alloy increases from 253 to 267.5 K and the maximum magnetic entropy change, vertical bar Delta S-m vertical bar, also increases from 36.36 to 44.35 J/kg K under 3 T magnetic field. Furthermore, the thermal hysteresis of M-T curves around T-C upon heating and cooling, a signature of a first-order magnetic phase transition, reduces from 15 K for as-sintered sample to 9 K for annealed sample. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3358620]
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JOURNAL OF APPLIED PHYSICS
ISSN: 0021-8979
年份: 2010
期: 9
卷: 107
3 . 2 0 0
JCR@2022
ESI学科: PHYSICS;
JCR分区:2
中科院分区:3