Dense　tungsten　bronze　Sr1.86Ca0.14NaNb5O15　piezoelectric　ceramic　is　prepared　by　CO2　laser　sintering　method　of　8　minute　duration.　Dielectric　examination　of　permittivity　disclose,　the　laser　sintered　ceramic　second　phase　transition　temperature　(Ts)　occurs　at　lower　temperature　than　furnace　sintered　ceramic　Ts.　The　observed　XRD　spectra　indicate　crystallographic　orientation　of　the　c-axes　as　being　perpendicular　to　the　laser　beam.　The　laser　sintered　Sr1.86Ca0.14NaNb5O15　ceramic　demonstrates　piezoelectric　properties　for:　maximum　reached　polarization　and　remnant　polarization,　Pm　=　8.9　C/cm2　and　Pr=　3.1　C/cm2,　coercive　field　Ec　=　10.1　kV/cm,　electromechanical　coupling　coefficient　k33=　27%.　The　piezoelectric　constant　d33　=　93　pC/N.