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Abstract:
A europium complex [Eu-2(bmd)(2)(Hbmd)(2)(H2O)(8)] center dot 8H(2)O (H(2)bmd=Benzimidazole-5,6-dicarboxylic acid) has been synthesized and structurally determined by X-ray diffraction single crystal structure analysis. The crystal belongs to triclinic, space grounp P (1) over bar, with a=0.754 49(15) nm, b=1.253 8(3) run, c=1.405 8(3) nm, alpha=71.03(3)degrees, beta=82.83(3)degrees, gamma=79.12(3)degrees, V=1.232 1(5) nm(3), Z=1. The complex is a binuclear compound and each E(III) ion is nine-coordinated. The versatile hydrogen bonds link binuclear units into a three-dimensional (3D) supermolecular network. Furthermore, the fluorescent properties of the complex have been investigated at room temperature. CCDC: 742510.
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN: 1001-4861
Year: 2009
Issue: 5
Volume: 25
Page: 924-928
0 . 7 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2