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The magnetic transition has been studied in Mn1.1Fe0.9P0.8Ge0.2 by magnetic measurements and Fe-57 Mossbauer spectroscopy. The alloy crystallizes in the hexagonal Fe2P-type structure with lattice constants of a=6.0476(4) angstrom and c=3.4766(7) angstrom. Both bulk magnetization measurements and Mossbauer spectroscopy show that the as-prepared sample has a significantly lower transition temperature on first cooling (T-C(1)approximate to 200 K) than after it has undergone thermal cycling to 20 K (T-C(20) (K)=240 K). The behavior of the material stabilizes after the first cooling/heating cycle and no further changes are observed in T-C. Working with a stabilized sample, we find that the temperature dependence of the hyperfine field, B-hf(T), is more rapid than that predicted by a simple mean field Brillouin function, and in addition, B-hf(T) shows a thermal hysteresis of 10 K upon cooling versus heating. These results show that the magnetic transition at T-C is definitely first order and suggest that there is an additional irreversible magnetostructural change during the first cooling process of the as-prepared sample. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3067496]
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JOURNAL OF APPLIED PHYSICS
ISSN: 0021-8979
年份: 2009
期: 7
卷: 105
3 . 2 0 0
JCR@2022
ESI学科: PHYSICS;
JCR分区:1
中科院分区:1