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Nitrate eutectic salts are widely applied as heat transfer and thermal energy storage medium for solar thermal power plant, and the corrosion of the nitrate eutectic salt to the system device has become challenge to the safety operation under high temperature. In this work, the dynamic corrosion behavior of 316 and 321 stainless steels in Solar Salt with the velocity of 1 m/s, 2 m/s and 3 m/s had been experimentally investigated at 565 degrees C under air atmosphere. The weight loss data showed that the velocity of molten salt had a significant influence on the corrosion process of 316 and 321 steel. The corrosion parabolic rate was obtained by the linear fitting, which showed slightly increasing with the increasing of flow velocity. The macro-characteristics, micro-morphology and the thickness of the multilayer corrosion product were observed and analyzed by the SEM and BEI. Meanwhile, the transformation with the outer elements of O, Fe, Mg and Na to O, Fe, Cr and Ni in the inner oxide layer was revealed in the multilayer oxide structure by EDS. It could be drawn that the corrosion resistance of the two stainless steels was highly affected by the passivation behavior of enrichment of Cr and Ni, which were observed in the inner oxide layer and confirmed as the mixed of (Fe, Cr, Ni)(3)O-4 by the XRD. In addition, the phenomenon of eroding and accelerated dissolution were observed on both stainless steels, which caused the increasing corrosion at dynamic environment.
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