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作者:

Zhou, Zhong-Liang (Zhou, Zhong-Liang.) | Kang, Tian-Fang (Kang, Tian-Fang.) (学者:康天放) | Zhang, Yan (Zhang, Yan.) | Cheng, Shui-Yuan (Cheng, Shui-Yuan.) (学者:程水源)

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Scopus SCIE

摘要:

A novel electrochemical sensor for the determination of formaldehyde is introduced based on electrodepositing nanostructured platinum-palladium alloy in Nafion film-coated glassy carbon electrode. Bimetallic Pt-Pd nanoparticles are found to be uniformly dispersed in Nafion film, as confirmed by scanning electron microscopic analysis. Energy dispersed X-ray analysis is used to characterize the composition of metal present in the nanoparticle-modified electrodes. The electrocatalytical behavior of the electrode is investigated by cyclic voltammetry and linear sweep voltammetry. Experimental results show that the electrode displays a remarked electrocatalytic activity for the oxidation of formaldehyde and exhibits a linear relationship in the range of 10 mu M to 1 mM, with a detection limit of 3 mu M in acidic solution. The low detection limit, wide linear range, and high sensitivity of the sensor make it valuable for further application.

关键词:

Electrocatalytic oxidation Nanoparticles Platinum-palladium alloy Formaldehyde

作者机构:

  • [ 1 ] [Zhou, Zhong-Liang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100022, Peoples R China
  • [ 2 ] [Kang, Tian-Fang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100022, Peoples R China
  • [ 3 ] [Zhang, Yan]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100022, Peoples R China
  • [ 4 ] [Cheng, Shui-Yuan]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100022, Peoples R China

通讯作者信息:

  • 康天放

    [Kang, Tian-Fang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100022, Peoples R China

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来源 :

MICROCHIMICA ACTA

ISSN: 0026-3672

年份: 2009

期: 1-2

卷: 164

页码: 133-138

5 . 7 0 0

JCR@2022

ESI学科: CHEMISTRY;

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 102

SCOPUS被引频次: 109

ESI高被引论文在榜: 0 展开所有

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