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摘要:
La-LaH2 nanopowders were prepared by hydrogen are plasma method, and then the mixed nanopowders of La-LaH2 and B were in situ sintered by Sparkle Plasma Sintering (SPS) method in oxygen free system. High-purity LaB6 polycrystal nonostructured bulk was successfully synthesized by SPS. The dehydrogenation of LaH2 nanopowders and the reaction equation of sintering LaB6 were studied. The phase and microstructure of LaB6 bulks were characterized by using XRD, SEM, TEM and AFM techniques. The results show that the dehydrogenation temperature of LaH2 nonopowders is 796.4 degrees C. The sintered body is single-phase LaB6, which has a high purity of 99.867%, and its relative densities is up to 99.2%. The hardness and bend strength of the sintered LaB6 are much better than those of LaB6 prepared by other sintering methods. The crystals of LaB6 Bulk are equiaxed crystals, the average grain size of the bulks sintered at 50MPs and 1250-1350 degrees C is about 120nm. The grains are homogenous and integrated, and the grain size increases with the raising of sintering temperature.
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JOURNAL OF INORGANIC MATERIALS
ISSN: 1000-324X
年份: 2008
期: 6
卷: 23
页码: 1199-1204
1 . 7 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
JCR分区:3