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作者:

Zhao Yan (Zhao Yan.) (学者:赵艳) | Li Dong (Li Dong.) (学者:李冬) | Lu Wen-Jing (Lu Wen-Jing.) | Wang Hong-Tao (Wang Hong-Tao.) | Piao Xue-Song (Piao Xue-Song.)

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Scopus SCIE PKU CSCD

摘要:

A supercritical water pretreatment was applied to cellulose dissolution and hydrolysis. The effects of temperature, residence time, and ratio of solid/liquid phase on the cellulose dissolution and sugar conversion were investigated. The results showed that cellulose could dissolve completely in a short time at 380 degrees C and higher temperature. The reaction temperature has significant effect on consequent hydrolyzation and sugar conversion in the range of 374 similar to 386 degrees C, and the highest concentration of oligosaccharides and hexoses was obtained around the critical point. On the other hand, these products were also decomposed rapidly under the supercritical condition with the extending of reaction time. The ratio of initial solid/liquid phase affects the cellulose hydrolyzation markedly as well. The best results were obtained with 40 mg cellulose/2.5 mL water at 380 degrees C and 16 s, affording oligosaccharide recovery above 29%, or 80 mg cellulose/2.5 mL water at 380 degrees C and 18 s, affording hexose recovery above 39%.

关键词:

cellulose glucose hydrolyzation oligosaccharide supercritical water

作者机构:

  • [ 1 ] [Zhao Yan]Tsinghua Univ, Dept Environm Sci & Technol, Beijing 100084, Peoples R China
  • [ 2 ] [Lu Wen-Jing]Tsinghua Univ, Dept Environm Sci & Technol, Beijing 100084, Peoples R China
  • [ 3 ] [Wang Hong-Tao]Tsinghua Univ, Dept Environm Sci & Technol, Beijing 100084, Peoples R China
  • [ 4 ] [Piao Xue-Song]Tsinghua Univ, Dept Environm Sci & Technol, Beijing 100084, Peoples R China
  • [ 5 ] [Li Dong]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100022, Peoples R China

通讯作者信息:

  • 赵艳

    [Zhao Yan]Tsinghua Univ, Dept Environm Sci & Technol, Beijing 100084, Peoples R China

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来源 :

ACTA CHIMICA SINICA

ISSN: 0567-7351

年份: 2008

期: 20

卷: 66

页码: 2295-2301

2 . 5 0 0

JCR@2022

ESI学科: CHEMISTRY;

JCR分区:3

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