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作者:

Yu Zhi-Hui (Yu Zhi-Hui.) | Xie Jia (Xie Jia.) | Xia Ding-Guo (Xia Ding-Guo.)

收录:

SCIE PKU CSCD

摘要:

SnO2-TiO2 thin films were deposited on the activated glassy carbon electrodes by vacuum coating method. Au-Pt/SnO2-TiO2/GC composite electrode was prepared by reducing HAuCl4 and H2PtCl6 mixture Solution and sediment Au-Pt bimetallic nanoparticles successively on the SnO2-TiO2/GC. The effect of SnO,-TiO, film support on the electrocatalytic properties of Au-Pt nanoparticles was characterized via cyclic voltograme method. The morphological and structural properties of Au-Pt nanoparticles self-assembled on SnO2-TiO2 film were characterized via Scanning Electron Microscope and X-ray Photoelectron Spectroscopy. The results show that the compact and uniformed 10 nm Au-Pt nanoparticles were self-assembled on SSnO2-TiO2 film. The ability of anti-CO poisoning was enhanced with the function of SnO2-TiO2 support. The form of Au-Pt alloy enhanced the electrocatalytic oxidation of methanol in acidic system. Furthermore, the increase of d vacancy with the function of SnO2-TiO2 support improved the stability and catalytic property of Au-Pt bimetallic nanoparticles.

关键词:

SnO2-TiO2 Oxidation of methanol Anti-CO poisoning Au-Pt nanoparticles

作者机构:

  • [ 1 ] [Yu Zhi-Hui]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Xie Jia]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Xia Ding-Guo]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 夏定国

    [Xia Ding-Guo]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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来源 :

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE

ISSN: 0251-0790

年份: 2008

期: 6

卷: 29

页码: 1190-1194

1 . 0 0 0

JCR@2022

ESI学科: CHEMISTRY;

JCR分区:3

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