Electrochemical　dechlorination　of　chloroform　in　neutral　aqueous　solution　was　investigated　using　palladium-loaded　electrodes　at　ambient　temperature.　Palladium/foam-nickel　(Pd/foam-Ni)　and　palladiuni/polymeric　pyrrole　film/foam-nickel　(Pd/PPy/foam-Ni)　composite　electrodes　which　provided　catalytic　surface　for　reductive　dechlorination　of　chloroform　in　aqueous　solution　were　prepared　using　an　electrodepositing　method.　Scanning　electron　microscope　(SEM)　micrographs　showed　that　polymeric　pyrrole　film　modified　the　electrode-surface　characteristics　and　resulted　in　the　uniform　dispersion　of　needle-shaped　palladium　particles　on　foam-Ni　supporting　electrode.　The　experimental　results　of　dechlorination　indicated　that　the　removal　efficiency　of　chloroform　and　current　efficiency　in　neutral　aqueous　solution　on　Pd/PPy/foam-Ni　electrode　could　be　up　to　36.8%　and　33.0%　at　dechlorination　current　of　0.1　mA　and　dechlorination　time　of　180　min,　which　is　much　higher　than　that　of　Pd/foam-Ni　electrode.