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Author:

Yi, Ding (Yi, Ding.) | Chen, Guanghua (Chen, Guanghua.) | Liu, Guohan (Liu, Guohan.) | Zhu, Xiuhong (Zhu, Xiuhong.) | Zhang, Wenli (Zhang, Wenli.) | Bin, He (Bin, He.) | Ma, Zhanjie (Ma, Zhanjie.) | He, Deyan (He, Deyan.)

Indexed by:

EI Scopus SCIE

Abstract:

Hydrogenated amorphous silicon (a-Si:H) films have been deposited with pure silane and then annealed with atomic hydrogen at lower temperature (T-s = 170 degrees C) in a novel, hot wire assisted microwave electron cyclotron resonant chemical vapor deposition system (HW-MWECR-CVD). The experimental results showed that the total hydrogen concentration (C-H) in the film decreased with H-2 flux increase in the atomic hydrogen anneal (AHA) step, but it does not obviously change, keeping at about 3% when H-2 flux increased to a higher value. This is due to double effects of AHA, the crystallization effect at lower substrate temperature and the rehydrogenation effect in low hydrogen concentration films. Furthermore, it was proposed that with increasing R (R = 1 /{F-hydrogen/(F-silane + F-hydrogen)}, in which F-silane is the silane gas flux in first film synthesis stage and F-hydrogen is the hydrogen gas flux during the annealing step, respectively.), polyhydrides such as SiHx (x = 2 or 3) turn into monohydrides SiH, which results in reducing the network defects, improving the film microstructure and decreasing the optical band gap from 1.644 to 1.557 eV. (C) 2006 Elsevier Ltd. All rights reserved.

Keyword:

crystallization microstructure rehydrogenation atomic hydrogen anneal (AHA) hydrogenated amorphous silicon (a-Si : H) films optical band gap

Author Community:

  • [ 1 ] Beijing Univ Technol, Dept Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 2 ] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China

Reprint Author's Address:

  • [Zhu, Xiuhong]Beijing Univ Technol, Dept Mat Sci & Engn, Beijing 100022, Peoples R China

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Source :

VACUUM

ISSN: 0042-207X

Year: 2007

Issue: 1

Volume: 82

Page: 105-108

4 . 0 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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