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By applying the spark plasma sintering technology, the Nd bulks with amorphous, amorphous and nanocrystalline mixed, and ultrafine nanocrystalline structures were prepared. The microstructures of the Nd bulks are characterized by HRTEM. The physical properties of the ultrafine nanocrystalline Nd bulk, such as the phase transformation features, the electrical resistivity, the thermal conductivity, and the coefficient of thermal expansion, as well as their evolution rules with the temperature, were measured and compared with those of the raw polycrystalline bulk. It was found that the temperature of transformation from hcp to bcc is 650 degrees C, which is reduced by 200 degrees C in comparison with the raw polycrystalline material. The electrical resistivity is obviously increased as compared with that of the polycrystalline bulk, while the thermal conductivity is remarkably decreased by about 3 times.
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