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作者:

Zhang Xin (Zhang Xin.) | Zhang Huxing (Zhang Huxing.) | Lu Qingmei (Lu Qingmei.) | Wei Qun (Wei Qun.) | Liu Danmin (Liu Danmin.) (学者:刘丹敏) | Liu Yanqin (Liu Yanqin.)

收录:

SCIE PKU CSCD

摘要:

The filled skutterudite compounds RE gamma(Fe/Ni)(x)Co4-xSb12 (x=0 similar to 1.0, y=0-0.4) were synthesized by solid state reaction and Spark Plasma Sintering (SPS) at 800 similar to 1000 K using the powders of Co, Sb, Fe, Ni and rare earth Ce and La as precursors. The effects of the kinds of filling and replacement atoms and the form of filling on the lattice thermal conductivity and thermo-electric property were discussed in this paper. The results indicate that the thermoconductivity is remarkably reduced by substituting Co with Ni and Fe, and Ni has a better effect on thermoconductivity in contrast with Fe. In addition, the lattice thermal conductivity is obviously decreased by filling with rare earth Ce and La into the Skutterudite structure. The decrease of lattice thermal conductivity is more effective by double fillings of Ce and La than single filling for the same filling fraction. The electric conductivity is decreasing and the Seebeck coefficient is increasing with the filling fraction of Ce and La increasing. The Skutterudite compound Ce0.1La0.2FeCo3Sb12 possesses the minimum thermal conductivity and the highest Seebeck coefficient with the highest ZT value of 0.6 at 800 K.

关键词:

filling lattice thermal conductivity skutterudite compounds SPS in-situ synthesis substitution

作者机构:

  • [ 1 ] Beijing Univ Technol, Beijing 100022, Peoples R China

通讯作者信息:

  • [Zhang Xin]Beijing Univ Technol, Beijing 100022, Peoples R China

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来源 :

RARE METAL MATERIALS AND ENGINEERING

ISSN: 1002-185X

年份: 2007

期: 6

卷: 36

页码: 968-972

0 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

JCR分区:3

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