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In this work, TiBa glass microspheres co-doped with Tm3+/Yb3+ for morphology-dependent resonances of upconversion emission were designed. The components of glass sample were 25TiO(2)-27BaCO(3)-8Ba(NO3)(2)-5ZnO(2)-8CaCO(3)-5H(3)BO(3)-9SiO(2)-7water glass-1Tm(2)O(3)-5Yb(2)O(3) (wt%). The emission spectra of TiBa bulk glass and the TiBa glass microsphere under 633 mn excitation were measured and discussed. The strong morphology-de pendent resonances of up-conversion fluorescence in the microsphere were observed. The observed resonances could be assigned by using the well-known Lorenz-Mie formalism. (c) 2006 Elsevier B.V. All rights reserved.
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